منابع مشابه
Metal Complexes as ligand : Binuclear Ni(II) and Cu(II) metal chelates of p-Methylisonitrosoacetophenone with Alkaline earth metal salts
A number of new binuclear complexes have been synthesised by interaction of stable Ni(II) and Cu(II) metal chelates of p-Methylisonitroacetosophenone with Alkaline earth metal salts having general formula[Ma(p-MeINAP)2MbL2 or MbX2]where Ma=Ni(II) or Cu(II),p-MeINAP = deprotonated pMethyiIsonitrosoacetophenone, Mb= Ca ++ or Mg ++ ,L = deprotonated ortho amino benzoic acid and 8hydroxyquinoline X...
متن کاملSpectroscopic evidence of Cu(II) and Zn(II) complexes having amino acid based Schiff base: A special emphasis on in vitro antimicrobial, DNA binding and cleavage studies
A new Schiff base ligand (L) obtained by the condensation reaction of N-acetylaceto-otoluidineand 2-aminopropanoic acid (an amino acid), is used to synthesize four mononuclearcomplexes of [MLCl] and [ML2] types (where M = Cu(II) and Zn(II); L = Schiff base) bykeeping the metal and ligand ratio as 1:1 and 1:2 respectively. This ligand and its complexeshave been characterized on the basis of diff...
متن کاملMetal (II) Complexes of Fluconazole: Thermal, XRD and Cytotoxicity Studies
We report thermal, X-ray diffraction (XRD) and cytotoxicity studies of complexes of fluconazole (FCZ) with Cu (II), Fe(II), Cd(II), Co(II), Ni(II), and Mn(II). From XRD measurements, FCZ and its metal complexes were identified as polycrystalline. Marked differences in the X-ray patterns of drug and its metal complexes revealed that the complexes are indeed different compounds and not just the m...
متن کاملMetal (II) Complexes of Fluconazole: Thermal, XRD and Cytotoxicity Studies
We report thermal, X-ray diffraction (XRD) and cytotoxicity studies of complexes of fluconazole (FCZ) with Cu (II), Fe(II), Cd(II), Co(II), Ni(II), and Mn(II). From XRD measurements, FCZ and its metal complexes were identified as polycrystalline. Marked differences in the X-ray patterns of drug and its metal complexes revealed that the complexes are indeed different compounds and not just the m...
متن کاملMetal chelates of glycine and glycine peptides.
Since the advancement by Smith et al. (l-4) of the theory that metal ions are chelated simultaneously to enzyme protein and substrate in various polypeptidases, the nature of metal binding to peptides and proteins has become an important as well as an interesting problem. The chelate structures proposed by Smith (3), and later somewhat revised (5, 6), indicate that the metal is bound, at least ...
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 1961
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.81.6_824